This fall, occurring around 1:00 P.M., was witnessed by two station workers who were opening a fence gate on the MillbillillieJundee track in Western Australia; however, no specimens were recovered until 1970. Searches by local Aborigines have produced many well-preserved, oriented specimens with the shiny black fusion crust that is characteristic of these calcium-rich meteorites. As with most eucrites, these stones contain calcium-bearing minerals such as plagioclase and augite, which, when mixed with free metal that has been oxidized to magnetite, and then rapidly quenched from the molten state, produces a black, glossy fusion crust (O.R. Norton, 2002). Millbillillie is among the most thermally equilibrated of the eucrites, a type 6 in the metamorphic sequence of Takeda and Graham (1991) and Yamaguchi et al. (1996). It contains a mixture of granulitic fragmental breccias and impact-melts, with a network of glassy veins and other shock features. It has been classified as a recrystallized polymict breccia containing lithologies of differing Mg# [= molar MgO/(MgO + FeO)] (Yamaguchi et al., 1994).
Type 1most rapidly cooled within the sequence; mesostasis-rich with a glass phase and original chemistry preserved; exhibits pronounced MgFe zoning in pyroxenes; represents the least altered basalt studied; e.g., clasts in Y-75011, Y-75015, and Y-74450
Type 2metastable Fe-rich pyroxenes are absent; mesostasis glass is no longer clear; e.g., Pasamonte
Type 3zoning from core to rim is less defined with an increase in Ca towards the rim; pyroxenes becoming cloudy; coarsening of pyroxenes resulting from augite exsolution lamellae; e.g., clast in Y-790266
Type 4only remnants of zoning still visible; cloudy pyroxenes present; mesostasis glass is recrystallized or absent; augite exsolution lamellae becoming resolvable in microprobe; e.g., Stannern, Nuevo Laredo
Type 5homogeneous host composition with readily resolvable exsolved pigeonite lamellae; pigeonites extensively clouded by reheating; mesostasis glass recrystallized or absent; e.g., Juvinas, Sioux Co., Lakangaon
Type 6most slowly cooled eucrites in the sequence; the clinopyroxene pigeonite is partly inverted to orthopyroxene through slow cooling processes; pyroxenes contain Mg-rich cores and coarse augite exsolution lamellae; original mesostasis is absent; Ca is enriched in the rims; often have a brecciated texture; e.g., Millbillillie, Y-791186
Type 7recognized as the most metamorphosed in the sequence (Yamaguchi et al., 1996); e.g., Palo Blanco Creek, Jonzac, Haraiya, A-87272, NWA 3152
In their paper, Not All Eucrites Are Monomict Breccias, Yamaguchiet al. (1997) concluded that Millbillillie, Sioux County, and several other eucrites previously believed to be monomict breccias are instead metamorphosed polymict eucrites. The variability in the clast textures suggests that many eucrites including Millbillillie are actually metamorphosed polymict breccias with a low abundance of exotic components. Additional evidence for this fact in Millbillillie is the presence of lithologies with significantly different Mg#, a likely result of brecciation events, probably at the floor of an impact crater, which was followed by homogenization and recrystallization of the clasts. Further evidence of a heterogeneous composition is the difference in 244PuXe ages in the components4.566 b.y. for the fine-grained component, and 4.507 b.y. for the coarse-grained component (Quitté et al., 31st LPSC (2000) #1441; Miura et al., 1998).
Mineralogical, geochemical, and petrological evidence compiled for Millbillillie suggests a formation chronology in which melting occurred very early, ~1.2 (± 1.2) m.y. after the closure of CAIs (Babechuk et al., 2010). According to AlMg systematics, core segregation occurred 2.5 (± 1.2) m.y. after CAIs (Schiller et al., 2010). Mantle fractionation occurred ~2 m.y. later and was followed by cratering processes that caused brecciation and mixing of fractionated impact melt with lithic fragments. This was then followed by a period of thermal annealing resulting in significant equilibration of the pyroxenes. A subsequent impact produced the network of glassy veins, which was then followed by another weak impact that produced fine microcracks. It has been established by ArAr dating that a significant impact event occurred ~3.55 b.y. ago, resetting the chronometer to match one of several age clusters common for eucrites.
Crater retention ages on Vesta calculated by Schmedemann et al. (2013 #2155) show an older cluster dated at 3.75 (+0.05/0.21) b.y. ago and a younger cluster dated at 3.58 (+0.07/0.12) b.y. ago. These ages also correspond to the ArAr ages of HED meteorites. Although Schmedemann et al. (2013) attributed these crater retention ages to the formation of the Veneneia and Rheasilvia basins, respectively, more recent studies place their ages at 2.1 b.y. and 1.0 b.y., respectively. These crater retention age clusters not only correspond to some of the measured HED age clusters, but also to the period of Late Heavy Bombardment that affected the Moon ~4.13.8 b.y. ago; however, these younger clusters attest to an extended period of bombardment on Vesta. Furthermore, the crater counting technique revealed a global age of ~4 b.y.
Millbillillie has a KrKr-based cosmic-ray exposure (CRE) age of 23.57 (±1.87) m.y., including it within the largest of five common breakup clusters established at 57, 1014, 1725, 3046 and 7076 m.y. Meteorite examples of each of these CRE age clusters are (in m.y.) 6.93 (±0.33) Bouvante, 12 (±2) Juvinas, 23.57 (±1.87) Millbillillie, 36.37 (±2.08) Stannern, and 6570 HaH 286. The ~22 m.y. old impact-ejection event was evidently a particularly large one given that it comprises about one-third of all HED meteorites and includes representatives of all HED meteorite types (cumulate, brecciated, unbrecciated, and polymict eucrites, diogenites, and howardites) ejected at that time (Wakefield et al., 2004 #1020 ; Bogard, 2009). In addition, the ~39 m.y. old impact-ejection event was statistically significant (Cartwright et al., 2012).
Some anomalous eucrites have similar CRE age values, including 26.71 m.y. for both Pasamonte and Bunburra Rockhole, and 12.5 (±0.52) m.y. for Ibitira. In a similar CRE age study also based on Kr-systematics, Strashnov et al. (2013) have determined those ages for a group of eucrite falls (including Millbillillie). Although they also concluded that the majority of these eucrites correspond to only five common impact events, which occurred within the past ~50 m.y., the clusters differed slightly from those outlined above. Their five cluster events are dated at 10.6 (±0.4), 14.4 (±0.6), 21.7 (±0.4), 25.4 (±0.4), and 37.8 (±0.6) m.y. ago.
The formation history of the howarditeeucritediogenite (HED) clan began with the early accretion of the parent asteroid, probably 4 Vesta, within ~1 m.y. of the first Solar System condensates. Based on its O-isotopic signature, the precursor material for this large asteroid is calculated to have had a chondritic H/CV-like (or possibly H/CR-like) composition (Rai et al., 2016). Within a short time the body began to melt from the heat of decay of short-lived radionuclides such as 26Al and 60Fe, in addition to impact-generated heating (John T. Wasson, 2016), eventually forming a magma ocean. Metalsilicate melting, differentiation, and fractionation then occurred 4.5649 (±0.0011) b.y. ago, or ~3 m.y. after CAI formation (based on MnCr systematics; Trinquier et al., 2008; AlMg systematics; Schiller et al., 2010). Notably, mesosiderite clasts have similar ages within error. An alternative timeline based on the HfW system in a model reflecting a low mantle Hf/W ratio suggests that differentiation leading to core metal segregation occurred no later than 1.2 (±1.2) m.y. after the closure of CAIs (Babechuk et al., 2009). Late accretion occurred within 2 m.y. of CAIs, but after core formation had occurred as evidenced by the finding of highly siderophile elements still remaining in diogenite mantle material (Day et al., 2012).
The metallic core of Vesta eventually attained a radius of ~5575 km. Active convective forces in the magma ocean promoted equilibrium crystallization conditions and initiated mantle fractionation, eventually leading to eucritic melts ~2.1 m.y. after CAIs. An olivine-rich dunite layer ~150 km thick initially crystallized around the metallic core. Recent studies of the unique 1.09 g olivine-rich (dunitic/harzburgitic?) achondrite QUE 93148 suggest that this might be a sample of the HED mantle layer (Goodrich and Righter, 2000; C. Floss, 2003), just as the dunitic meteorites NWA 2968 (Bunch et al., 2006) and MIL 03443 (D. Mittlefehldt, 2008; Greenwood et al., 2015) are thought to be. However, due to its lower Co and Ni abundances than what would otherwise be expected for an olivine-rich mantle lithology or magma ocean cumulate, other teams (Shearer et al., 2008; Shearer et al., 2010) have suggested that QUE 93148 originated on a distinct planetary body such as that of the main-group pallasites. Furthermore, Hahn et al. (2018) studied orthopyroxenechromite symplectites in QUE 93148 as well as its geochemistry, and they contend that the meteorite is probably a mantle residue derived from a high degree of melting and is likely is related to harzburgite clasts present in some howardites. Yet, the symplectites in QUE 93148 have been compared by Vaci et al. (2020, #1751) to those in the ungrouped dunite breccia NWA 12217/12562/12319, and they argue that the similar mineralogy and petrology of these meteorites suggest a possible genetic link.
Basaltic volcanism occurred very soon after differentiation of the parent bodywithin a short interval commencing as early as ~7 m.y. after the formation of the Solar System, and spanning a period no longer than 17 m.y. (Misawa et al., 2005). Micron-sized zircons, associated with ilmenite, have been studied from various eucrites to obtain an accurate crystallization age. The 207Pb206Pb ages for these zircons of ~4.554 (±0.020) b.y. represent the crystallization ages of extrusive eucritic lavas. However, it has been found that this crystallization event is best dated by zircons from the eucrite Igdi since those derived from Millbillillie reflect a slightly later volcanism or disturbance at 4.543 (±0.015) b.y. (Lee et al., 2009). Coincidentally, this eucrite thermal event occurred during the time period in which the Moon is considered to have formedin the Giant Impact 30110 m.y. after the beginning of the Solar System (Hopkins and Mojzsis, 2012).
Next in the sequence to crystallize was a cumulate, orthopyroxene-rich, diogenite layer at least 13 km thick. Ultimately, residual liquids which were subjected to fractional crystallization (Holzheid and Palme, 2007) were extruded onto the surface. This period of volcanism produced basalt flows that solidified to form a thin crust ~1015 km thick (Mayne et al., 2008; Wasson, 2012). This basaltic crustal rock was buried in turn by continual insulating flows of lava, resulting in its reheating and metamorphism and eventual formation of the Main GroupNuevo Laredo trend eucrites. The late-stage ascent of a portion of this Main Group magma was contaminated with a crustal partial melt to become the incompatible-element-rich Stannern trend eucrites.
Some of the residual liquid, or more likely a separate REE-enriched liquid, was trapped at depths of up to ~10 km and underwent late fractionation and re-equilibration processes to produce the cumulate eucrites, dated at ~60100 m.y. after CAI formation based on HfW, SmNd, and LuHf systematics (Touboul et al., 2008). Thereafter, surface eucritic material was impact brecciated to form a regolith, which was combined with chondritic and diogenitic clasts and lithified to form the polymict howardite members of the HED clan (additional classification information for the HED clan can be found on the Kapoeta page).
Vesta has an average diameter of ~506 km, with an outer basaltic crust thin enough (~1525 km) to have been completely excavated down to diogenitic material by an impactor ~3744 km in diameter traveling 5.5 km/sec (Ivanov and Kamyshenkov, 2013). The resulting impact basin near the south pole, named Rheasilvia (after the mother of Romulus and Remus, the mythical mother of the Vestals), is ~460 km wide and ~20 km deep. Some investigators believe this excavation event occurred ~4.48 b.y. ago, while others provide evidence for a significantly more recent event consistent with the fact that the Vestoids remain in close proximity.
3-D image of Vesta (Anaglyph Red/Blue); credit: NASA's Dawn Spacecraft
See the Dawn Low-Altitude Mapping Orbit-derived Global Geologic Map of Vesta (pdf format)Williams et al., #1126 (2015)
Many shallower impacts into eucrite layers also occurred between 4.1 and 3.5 b.y. ago which reset many radiometric chronometers (Bogard and Garrison, 2003). Some of the eucrite, diogenite, and howardite material was spalled into space by these impacts and was entrained deep into the 3:1 and ν6 resonances. Searches have identified over 1,000 small (< 10 km in diameter) Vesta-like asteroids (Vestoids) composed of both eucritic and diogenitic fragments, which are thought to have been created by a late impact event 3.5 b.y. ago (Scott et al., 2009). Some of these Vestoids bridge the gap between Vesta and the 3:1 resonance gap. From the various dynamical escape hatches, Vestoids like the near-Earth asteroids 1983 RD, 1980 PA, and 1985 DO2, were perturbed into Earth-crossing orbits on time scales of tens to hundreds of m.y. Exposure age distributions of a statistical sampling of HED meteorites show that at least two major impact events occurred around 22 m.y. and 39 m.y. ago on one or more of these Vestoids.
The basaltic eucrite Bunburra Rockhole, which was tracked by the Desert Fireball Network as it fell in Western Australia in 2007, was recovered during an organized field search in 2008 (Bland et al., 2009). Its precisely calculated orbit is consistent with an Aten-type asteroid with a semi-major axis <1 AU. Interestingly, all petrographic characteristics studied so far are similar to the known basaltic eucrites (Spivak-Birndorf et al., 2010). However, Bunburra Rockhole has O- and Cr-isotopic compositions distinct from that of Vesta-derived eucrites, and therefore it is thought to represent a unique basaltic parent asteroid (e.g., Towner et al., 2010, Benedix et al., 2017). Bunburra Rockhole was likely delivered from the inner main belt through the ν6 secular resonance, demonstrating how material ejected from Vesta and the related Vestoids can be delivered to Earth in a like manner through an evolving orbit. Moreover, although Bunburra Rockhole and the ungrouped eucrite-like achondrite A-881394 have the same oxygen and chromium isotope compositions, new in-depth analyses of Bunburra Rockhole conducted by Benedix et al. (2017, and references therein) have revealed that these two meteorites have very different textures and mineral chemistries; e.g., Bunburra Rockhole has plagioclase with An8790, while A-881394 has plagioclase with An98. Based on their results, they consider it likely that these two meteorites derive from separate parent bodies. Further details about the anomalous eucrites can be found on the Pasamonte page.
The general composition of eucrites consists of roughly equal amounts of anorthite, a plagioclase feldspar, and the clinopyroxene called pigeonite. The source magma was probably derived from the mafic mineral peridotite, a mixture of olivine, pigeonite, and plagioclase, and is the mineral forming the bulk of the Earth's upper mantle. The age of eucrite crystallization is ~4.5 b.y., no later than ~16.2 m.y. after the formation of Allende CAIs. Cooling and metamorphism within an ejecta blanket lasted ~600 m.y. longer. The photo of Millbillillie above shows an 8.4 g oriented individual with radial flow lines, along with a 4.0 g partial slice showing the interior, coarse-grained texture consisting of anorthite and pigeonite.